Palladium & weak base kits

 

These kits are composed of 0.3 ml vials loaded with a catalyst and a weak base. The reagents are weighed individually and conditioned under inert condition. We offer a choice of arrays that allows to easily screen reaction conditions within few hours. Each included 2 set of reagents.

vials_holder

Catalysts and Bases Array

Available Palladium weak base arrays

 

HCK1004-01-002: 5 Catalysts and 3 bases combinations premixed in same vial. (30 vials total)

HCK1004-01-004: 8 Catalysts and 3 bases combinations premixed in same vial. (48 vials total)

 

Substrate 15 µmol Weak Bases 30 µmol (2 eq)
Precatalysts 1.5 µmol (10%) K2CO3 Cs2CO3 K3PO4
BrettPhosG2
RuPhosG2 Primary array
 XPhosG2 HCK1004-01-002
tBuXPhosG3 5 Catalysts & 3 Bases
tBuBrettG3
Pd2dba3/dppf Extended array
Pd(PtBu3)2 HCK1004-01-004
Pd(OAc)2/CataCXium® 8 Catalysts & 3 Bases

 

HCK1004-01-006: 8 Catalysts and 3 bases combinations premixed in same vial. (48 vials total)

HCK1004-01-007: 8 Catalysts and 4 bases combinations premixed in same vial. (64 vials total)

HCK1004-01-008: 8 Catalysts and 3 bases combinations premixed in same vial. (48 vials total)

HCK1004-01-009: 8 Catalysts and 4 bases combinations premixed in same vial. (64 vials total)

 

Substrate 15 µmol Weak Bases 30 µmol (2eq)
Precatalysts 1.5 µmol (10%) K2CO3 Cs2CO3 K3PO4 KOAc
BrettPhosG2

Primary array

 HCK1004-01-006

8 catalysts & 3 bases

Extended array

 HCK1004-01-007

8 catalysts

&

4 bases

RuPhosG2
XPhosG2
tBuXPhosG3
tBuBrettG3
AmphosG3
AdBrettPhosG3
CataCXium® A G3
DavePhosG3

Primary array

 HCK1004-01-008

8 catalysts & 3 bases

Extended array

 HCK1004-01-009

8 catalysts

&

4 bases

JackiePhosG3
JosiPhosG3
P(t-Bu)3G4
PCy3G4
RockPhosG3
SPhosG3
XantphosG3

Protocol:

pdweakbaseprocess